A void is the volume of space in a material such as sand or gravel not occupied by particles. The volume of voids is made up of tiny gaps between particles of the material. Calculating the volume of voids can be complex, requiring hightech tools such as measuring lasers. In other situations, like the one described here, calculating the volume of voids is fairly simple. You have to first determine the specific gravity of the material in question. Specific gravity is the ratio of the density of a substance to the density of water (equal to 1 g/ml).
Things You'll Need
 1,000 ml graduated container
 Precision scale
 Water
 Sand or other material
 Calculator
 Straightedge

Fill a 1,000 ml graduated container about half full of water. Weigh the container using a scale calibrated in grams. Record the weight and the exact volume of water in the container.

Add enough sand to bring the overall level in the container to about 3/4 full. Weigh the container again and record the weight and the volume of material now in the container.

Subtract the original weight (water only) from the weight of sand plus water to find the increase in weight. Subtract the original water volume from the volume of sand plus water to find the increase in volume.

Divide the increase in weight by the increase in volume to find the specific gravity of the sand. For example, if the weight of sand plus water was 450 g more than of the water alone and the volume increase was 180 ml, you have a specific gravity of 450/180 = 2.5.

Empty and dry the container thoroughly. Weigh the empty container. Fill the container to the 1,000 ml mark with dray sand. Use a straightedge to smooth the surface of the sand so it is level.

Weigh the container of sand and subtract the weight of the empty container to find the weight of the sand. Divide the weight by the volume (1,000 ml) to find the density of the sand. For example, if the sand weighs 1,500 grams, the density is 1.5.

Subtract the density of the sand from the specific gravity of the sand, then divide the result by the specific gravity to find the voidage (proportion of empty space in the dry sand). For example, with a density for dry sand of 1.5 and a specific gravity of 2.5, you have a voidage of (2.5 – 1.5)/2.5 = 0.4.

Multiply the voidage by the volume of the dry sand to find the volume of the void. With 1,000 ml of dry sand and a voidage of 0.4, you have a void volume of 400 ml.
References
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